High-frequency acoustic modes in liquid gallium at the melting point.

ABSTRACT

The microscopic dynamics in liquid gallium at melting has been studied by inelastic x-ray scattering. We demonstrate the existence of acousticlike modes up to wave vectors above one-half of the first maximum of the static structure factor, at variance with earlier results from inelastic neutron scattering [F. J. Bermejo et al., Phys. Rev. E 49, 3133 (1994)]. Despite structural (extremely rich polymorphism) and electronic (mixed valence) peculiarities, the collective dynamics is strikingly similar to the one of van der Waals and metallic fluids. This result speaks in favor of the universality of the short time dynamics in monatomic liquids rather than of system-specific dynamics.