A stereoselective cyclization to carbafuranose derivatives starting from 1,4-bis-epoxides.
Org Lett
; 7(23): 5183-6, 2005 Nov 10.
Article
in En
| MEDLINE
| ID: mdl-16268533
ABSTRACT
[reactions see text] A concise synthesis of highly functionalized cyclopentane derivatives via a Brook rearrangement mediated stereoselective linchpin cyclization reaction involving tert-butyldimethylsilyl-1,3-dithianyllithium and homochiral 1,4-bis-epoxides is described.
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Collection:
01-internacional
Database:
MEDLINE
Main subject:
Organometallic Compounds
/
Pentoses
/
Epoxy Compounds
Language:
En
Journal:
Org Lett
Journal subject:
BIOQUIMICA
Year:
2005
Document type:
Article
Affiliation country:
Reino Unido