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A stereoselective cyclization to carbafuranose derivatives starting from 1,4-bis-epoxides.
Leung, Leo M H; Boydell, A James; Gibson, Vicky; Light, Mark E; Linclau, Bruno.
Affiliation
  • Leung LM; School of Chemistry, University of Southampton, Highfield, Southampton SO17 1BJ, United Kingdom.
Org Lett ; 7(23): 5183-6, 2005 Nov 10.
Article in En | MEDLINE | ID: mdl-16268533
ABSTRACT
[reactions see text] A concise synthesis of highly functionalized cyclopentane derivatives via a Brook rearrangement mediated stereoselective linchpin cyclization reaction involving tert-butyldimethylsilyl-1,3-dithianyllithium and homochiral 1,4-bis-epoxides is described.
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Collection: 01-internacional Database: MEDLINE Main subject: Organometallic Compounds / Pentoses / Epoxy Compounds Language: En Journal: Org Lett Journal subject: BIOQUIMICA Year: 2005 Document type: Article Affiliation country: Reino Unido
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Collection: 01-internacional Database: MEDLINE Main subject: Organometallic Compounds / Pentoses / Epoxy Compounds Language: En Journal: Org Lett Journal subject: BIOQUIMICA Year: 2005 Document type: Article Affiliation country: Reino Unido