Kinetic modeling of adsorption of di-2-pyridylketone salicyloylhydrazone on silica gel.
J Colloid Interface Sci
; 307(1): 24-8, 2007 Mar 01.
Article
in En
| MEDLINE
| ID: mdl-17187817
ABSTRACT
The kinetics of DPKSH (di-2-pyridylketone salicyloylhydrazone) adsorption onto silica gel has been investigated at (25+/-1) degrees C and pH 1 and 4.7. The kinetics of adsorption of DPKSH is discussed using three kinetic models, the first-order Lagergren model, the pseudo-second-order model, and the intraparticle diffusion model. The adsorption of DPKSH, at pH 1 and 4.7, onto silica gel proceeds according to the pseudo-second-order model and the correlation coefficients were very close to 1. The intraparticle diffusion of DPKSH molecules within the silica gel particles was identified as the rate-limiting step. The parameters of the pseudo-second-order model are q(max,calc)=1.02 x 10(-4) and 1.5 x 10(-4) g DPKSH/g silica; k(2)=3.01 x 10(4) and 9.67 x 10(4) h(-1)g silica/g DPKSH, respectively, for pH 1 and 4.7.
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Collection:
01-internacional
Database:
MEDLINE
Main subject:
Pyridines
/
Silicon Dioxide
/
Hydrazones
/
Models, Chemical
Language:
En
Journal:
J Colloid Interface Sci
Year:
2007
Document type:
Article
Affiliation country:
Brasil