A metal-complex-tolerant CuAAC 'click' protocol exemplified through the preparation of homo- and mixed-metal-coordinated [2]rotaxanes.
Chem Commun (Camb)
; (41): 4218-20, 2007 Nov 07.
Article
in En
| MEDLINE
| ID: mdl-18217585
ABSTRACT
A series of mono- and bis-metallated [2]rotaxanes has been prepared using a CuAAC 'click' protocol that is compatible with metal-coordinated building blocks and ligands; the methodology provides a general means for appending a metal ion or complex to an organic scaffold via Cu(I)-catalysed 'click' chemistry, even when the molecule contains redox-active or kinetically labile metals or vacant ligand sites.
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Collection:
01-internacional
Database:
MEDLINE
Main subject:
Organometallic Compounds
/
Copper
/
Rotaxanes
Language:
En
Journal:
Chem Commun (Camb)
Journal subject:
QUIMICA
Year:
2007
Document type:
Article
Affiliation country:
Reino Unido