Bis[µ-2-(2,4-difluoro-phen-yl)-1,3-bis-(1,2,4-triazol-1-yl)propan-2-olato-κN,O:O,N]bis-[(acetato-κO,O')nickel(II)] methanol hemisolvate.
Acta Crystallogr Sect E Struct Rep Online
; 66(Pt 1): m75-6, 2009 Dec 19.
Article
in En
| MEDLINE
| ID: mdl-21579969
ABSTRACT
In the title complex, [Ni(2)(C(13)H(11)F(2)N(6)O)(2)(C(2)H(3)O(2))(2)]·0.5CH(3)OH, there are two half-molecules in the asymmetric unit. The two centrosymmetrically related Ni(II) atoms, each attached to an acetate ligand, are linked by two fluconazole ligands. Each Ni(II) atom is six-coordinated in a distorted octa-hedral geometry by two N atoms of the triazole groups and two bridging O atoms from two different fluconazole ligands and two O atoms from a chelating acetate ligand. In the crystal structure, the half-occupied methanol solvent mol-ecule is linked to a triazole group via an O-Hâ¯N hydrogen bond.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Acta Crystallogr Sect E Struct Rep Online
Year:
2009
Document type:
Article