Resonant inelastic x-ray scattering of methyl chloride at the chlorine K edge.
J Chem Phys
; 136(2): 024319, 2012 Jan 14.
Article
in En
| MEDLINE
| ID: mdl-22260591
ABSTRACT
We present a combined experimental and theoretical study of isolated CH(3)Cl molecules using resonant inelastic x-ray scattering (RIXS). The high-resolution spectra allow extraction of information about nuclear dynamics in the core-excited molecule. Polarization-resolved RIXS spectra exhibit linear dichroism in the spin-orbit intensities, a result interpreted as due to chemical environment and singlet-triplet exchange in the molecular core levels. From analysis of the polarization-resolved data, Cl 2p(x, y) and 2p(z) electronic populations can be determined.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Main subject:
Quantum Theory
/
Chlorine
/
Methyl Chloride
Language:
En
Journal:
J Chem Phys
Year:
2012
Document type:
Article
Affiliation country:
Francia