From competition to cooperation: a highly efficient strategy towards well-defined (co)polypeptides.
Chem Commun (Camb)
; 51(17): 3663-6, 2015 Feb 28.
Article
in En
| MEDLINE
| ID: mdl-25643829
ABSTRACT
By associating primary (slow but controlled ring-opening polymerization; ROP) and tertiary (fast but uncontrolled ROP) amines in the same molecule, a novel highly active organocatalytic system proceeding by an accelerated amine mechanism through monomer activation (AAMMA) and leading to living ROP of α-amino acid N-carboxyanhydrides at room temperature was successfully developed.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Main subject:
Peptides
/
Amines
/
Amino Acids
/
Anhydrides
Language:
En
Journal:
Chem Commun (Camb)
Journal subject:
QUIMICA
Year:
2015
Document type:
Article