Donor-acceptor organo-imido polyoxometalates: high transparency, high activity redox-active NLO chromophores.
Dalton Trans
; 45(7): 2818-22, 2016 Feb 21.
Article
in En
| MEDLINE
| ID: mdl-26815652
ABSTRACT
We show that polyoxometalates (POMs) are an excellent redox-active acceptor on which to base high performance 2(nd) order non-linear optical (NLO) chromophores. This is demonstrated through three new organoimido-Lindqvist derivatives with HRS ß0-values exceeding those of any dipolar organic system with comparable donor, π-system and absorption profile. Thus, organoimido POMs may provide a new generation of high performance, high transparency, and potentially redox-switchable NLO materials.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Dalton Trans
Journal subject:
QUIMICA
Year:
2016
Document type:
Article
Affiliation country:
Reino Unido