Rh-Catalyzed annulations of N-methoxybenzamides with ketenimines: synthesis of 3-aminoisoindolinones and 3-diarylmethyleneisoindolinones with strong aggregation induced emission properties.

Zhou, Xiaorong; Peng, Zhixing; Zhao, Hongyang; Zhang, Zhiyin; Lu, Ping; Wang, Yanguang

Zhou, Xiaorong; Peng, Zhixing; Zhao, Hongyang; Zhang, Zhiyin; Lu, Ping; Wang, Yanguang.

Affiliation

Zhou X; Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China. pinglu@zju.edu.cn orgwyg@zju.edu.cn.
Peng Z; Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China. pinglu@zju.edu.cn orgwyg@zju.edu.cn.
Zhao H; Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China. pinglu@zju.edu.cn orgwyg@zju.edu.cn.
Zhang Z; Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China. pinglu@zju.edu.cn orgwyg@zju.edu.cn.
Lu P; Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China. pinglu@zju.edu.cn orgwyg@zju.edu.cn.
Wang Y; Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China. pinglu@zju.edu.cn orgwyg@zju.edu.cn.

Chem Commun (Camb) ; 52(70): 10676-9, 2016 Aug 23.

Article in En | MEDLINE | ID: mdl-27507583

ABSTRACT

Rhodium-catalyzed C-H activation/annulation reactions of ketenimines with N-methoxybenzamides furnished 3-aminoisoindolin-1-ones and 3-(diarylmethylene)isoindolin-1-ones. The synthesized 3-(diarylmethylene)isoindolin-1-ones exhibited aggregation induced emissions in aqueous tetrahydrofuran solution and strong green-yellow emissions in solids.

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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2016 Document type: Article Country of publication: Reino Unido

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