Synthesis of Orthorhombic Perovskite-Type ZnSnO3 Single-Crystal Nanoplates and Their Application in Energy Harvesting.
ACS Appl Mater Interfaces
; 9(9): 8271-8279, 2017 Mar 08.
Article
in En
| MEDLINE
| ID: mdl-28211675
ABSTRACT
In recent years, lead-free piezoelectric nanogenerators have attracted much attention because of their great potential for harvesting energy from the environment. Here, we report the first synthesis of two-dimensional (2D) single-crystal ZnSnO3 hexagon nanoplates and the fabrication of ZnSnO3 nanoplate-based nanogenerators. The orthorhombic perovskite-structured ZnSnO3 nanoplates with (111) facets of the exposed plate surface are successfully synthesized via a one-step hydrothermal reaction. Piezoelectric nanogenerators are then fabricated using the as-synthesized single-crystal ZnSnO3 nanoplates and poly(dimethylsiloxane) (PDMS). A d33 value as high as 49 pC/N for the ZnSnO3@PDMS composite was obtained without any electrical poling process, which demonstrates that the single-crystal ZnSnO3 nanoplates have a single-domain structure. To the best of our knowledge, this d33 value is also the highest among lead-free piezoelectric composites. A bending strain can induce the piezoelectric nanogenerator (PENG) to generate a large, stable, and sustainable output open circuit voltage of 20 V and a short circuit current of 0.6 µA, which are higher than many other PENGs. The output signals are sufficient to light a single light-emitting diode (LED), which shows the great potential of the material for scavenging mechanical energy from moving entities, such as road vehicles, railway vehicles, and humans.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
ACS Appl Mater Interfaces
Journal subject:
BIOTECNOLOGIA
/
ENGENHARIA BIOMEDICA
Year:
2017
Document type:
Article