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DBU-catalyzed, aromatization-oriented, regioselective domino synthesis of 2-aminopyrimidines from ß-dicarbonyl compounds, DMF-DMA, and cyanamide.
Üngören, Sevket Hakan; Boz, Serife.
Affiliation
  • Üngören SH; Department of Chemistry, Faculty of Art and Science, Bozok University, 66200, Atatürk Yolu, Yozgat, Turkey. shakan.ungoren@bozok.edu.tr.
  • Boz S; Department of Chemistry, Faculty of Art and Science, Bozok University, 66200, Atatürk Yolu, Yozgat, Turkey.
Mol Divers ; 21(4): 925-932, 2017 11.
Article in En | MEDLINE | ID: mdl-28766257
ABSTRACT
A multicomponent domino synthesis has been developed for the preparation of 2-aminopyrimidines from ß-dicarbonyl compounds, N,N-dimethylformamide dimethyl acetal, and cyanamide. The protocol was used for the regioselective preparation of 4-amide/ester/ketone substituted 2-aminopyrimidines. Twelve 2-aminopyrimidines were isolated in good yields (56-93%).
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Pyrimidines / Cyanamide / Dimethylformamide Language: En Journal: Mol Divers Journal subject: BIOLOGIA MOLECULAR Year: 2017 Document type: Article Affiliation country: Turquía
Fulltext
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Pyrimidines / Cyanamide / Dimethylformamide Language: En Journal: Mol Divers Journal subject: BIOLOGIA MOLECULAR Year: 2017 Document type: Article Affiliation country: Turquía