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Covalent self-assembly of the specific RSSR isomer of 14-membered tetrakisphosphine.
Wittmann, T I; Musina, E I; Krivolapov, D B; Litvinov, I A; Kondrashova, S A; Latypov, Sh K; Karasik, A A; Sinyashin, O G.
Affiliation
  • Wittmann TI; A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia. elli@iopc.ru.
  • Musina EI; A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia. elli@iopc.ru.
  • Krivolapov DB; A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia. elli@iopc.ru.
  • Litvinov IA; A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia. elli@iopc.ru.
  • Kondrashova SA; A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia. elli@iopc.ru.
  • Latypov SK; A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia. elli@iopc.ru.
  • Karasik AA; A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia. elli@iopc.ru.
  • Sinyashin OG; A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia. elli@iopc.ru.
Dalton Trans ; 46(37): 12417-12420, 2017 Sep 26.
Article in En | MEDLINE | ID: mdl-28862706
ABSTRACT
The first representative of the specific RSSR isomer of 14-membered tetrakisphosphine has been obtained instead of the RRRR/SSSS isomer predicted according to the empirical rule formulated recently. The geometry of the obtained 14-P4N2 is preorganized for the dicopper complex formation with the unique coordination mode in the row of P4N2 corands.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Dalton Trans Journal subject: QUIMICA Year: 2017 Document type: Article Affiliation country: Rusia
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Dalton Trans Journal subject: QUIMICA Year: 2017 Document type: Article Affiliation country: Rusia