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Single-molecule conductance investigation of BDT derivatives: an additional pattern found to induce through-space channels beyond π-π stacking.
Li, Yunchuan; Xiao, Bohuai; Chen, Rongsheng; Chen, Haijian; Dong, Jianqiao; Liu, Yichong; Chang, Shuai.
Affiliation
  • Li Y; The State Key Laboratory of Refractories and Metallurgy, and Institute of Advanced Materials and Nanotechnology, Wuhan University of Science and Technology, Wuhan 430081, China. schang23@wust.edu.cn.
  • Xiao B; The State Key Laboratory of Refractories and Metallurgy, and Institute of Advanced Materials and Nanotechnology, Wuhan University of Science and Technology, Wuhan 430081, China. schang23@wust.edu.cn.
  • Chen R; The State Key Laboratory of Refractories and Metallurgy, and Institute of Advanced Materials and Nanotechnology, Wuhan University of Science and Technology, Wuhan 430081, China. schang23@wust.edu.cn.
  • Chen H; The State Key Laboratory of Refractories and Metallurgy, and Institute of Advanced Materials and Nanotechnology, Wuhan University of Science and Technology, Wuhan 430081, China. schang23@wust.edu.cn.
  • Dong J; The State Key Laboratory of Refractories and Metallurgy, and Institute of Advanced Materials and Nanotechnology, Wuhan University of Science and Technology, Wuhan 430081, China. schang23@wust.edu.cn.
  • Liu Y; The State Key Laboratory of Refractories and Metallurgy, and Institute of Advanced Materials and Nanotechnology, Wuhan University of Science and Technology, Wuhan 430081, China. schang23@wust.edu.cn.
  • Chang S; The State Key Laboratory of Refractories and Metallurgy, and Institute of Advanced Materials and Nanotechnology, Wuhan University of Science and Technology, Wuhan 430081, China. schang23@wust.edu.cn.
Chem Commun (Camb) ; 55(57): 8325-8328, 2019 Jul 11.
Article in En | MEDLINE | ID: mdl-31257366
ABSTRACT
The through-space conductance of individual molecules is supposed to improve the macroscopic carrier movement, but the most widely acclaimed through-space conductance channel just existed in sufficiently close π-π stacked benzene rings. As a breakthrough to this primary cognition, additional conducting channels were confirmed to exist in non-strict face-to-face aligned thiophenes or phenyl-thiophene in BDT derivatives for the first time.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2019 Document type: Article Affiliation country: China
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2019 Document type: Article Affiliation country: China