Facile synthesis of novel lithium ß-diketonate glyme adducts: the effect of molecular engineering on the thermal properties.

Peddagopu, Nishant; Rossi, Patrizia; Bonaccorso, Carmela; Bartasyte, Ausrine; Paoli, Paola; Malandrino, Graziella

Peddagopu, Nishant; Rossi, Patrizia; Bonaccorso, Carmela; Bartasyte, Ausrine; Paoli, Paola; Malandrino, Graziella.

Affiliation

Peddagopu N; Dipartimento di Scienze Chimiche, Università di Catania and INSTM UdR Catania, V.le Andrea Doria 6, 95125 Catania, Italy. gmalandrino@unict.it.
Rossi P; Dipartimento di Ingegneria Industriale, Università di Firenze, Via Santa Marta 3, 50136 Firenze, Italy.
Bonaccorso C; Dipartimento di Scienze Chimiche, Università di Catania, V.le Andrea Doria 6, 95125 Catania, Italy.
Bartasyte A; FEMTO-ST Institute, University of Bourgogne Franche-Comté CNRS UMR 6174, 26 Rue de l'Epitaphe, F-25030 Besançon, France.
Paoli P; Dipartimento di Ingegneria Industriale, Università di Firenze, Via Santa Marta 3, 50136 Firenze, Italy.
Malandrino G; Dipartimento di Scienze Chimiche, Università di Catania and INSTM UdR Catania, V.le Andrea Doria 6, 95125 Catania, Italy. gmalandrino@unict.it.

Dalton Trans ; 49(4): 1002-1006, 2020 Jan 28.

Article in En | MEDLINE | ID: mdl-31932829

ABSTRACT

ABSTRACT

Novel adducts of lithium hexafluoroacetylacetonato {Li(hfa)} with polyethers (monoglyme = {CH3OCH2CH2OCH3}, diglyme = {CH3O(CH2CH2O)2CH3}, triglyme = {CH3O(CH2CH2O)3CH3} and tetraglyme {CH3O(CH2CH2O)4CH3} have been synthesized through a single step reaction and characterized by FT-IR spectroscopy, 1H, and 13C NMR, single crystal X-ray diffraction studies along with thermal analysis.

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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Dalton Trans Journal subject: QUIMICA Year: 2020 Document type: Article Affiliation country: Italia

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