Ultraintense, ultrashort pulse X-ray scattering in small molecules.
Faraday Discuss
; 228(0): 139-160, 2021 May 27.
Article
in En
| MEDLINE
| ID: mdl-33576361
ABSTRACT
We examine X-ray scattering from an isolated organic molecule from the linear to nonlinear absorptive regime. In the nonlinear regime, we explore the importance of both the coherent and incoherent channels and observe the onset of nonlinear behavior as a function of pulse duration and energy. In the linear regime, we test the sensitivity of the scattering signal to molecular bonding and electronic correlation via calculations using the independent atom model (IAM), Hartree-Fock (HF) and density functional theory (DFT). Finally, we describe how coherent X-ray scattering can be used to directly visualize femtosecond charge transfer and dissociation within a single molecule undergoing X-ray multiphoton absorption.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Faraday Discuss
Journal subject:
QUIMICA
Year:
2021
Document type:
Article