Structural insight into [Fe-S2-Mo] motif in electrochemical reduction of N2 over Fe1-supported molecular MoS2.
Chem Sci
; 12(2): 688-695, 2020 Nov 12.
Article
in En
| MEDLINE
| ID: mdl-34163801
ABSTRACT
The catalytic synthesis of NH3 from the thermodynamically challenging N2 reduction reaction under mild conditions is currently a significant problem for scientists. Accordingly, herein, we report the development of a nitrogenase-inspired inorganic-based chalcogenide system for the efficient electrochemical conversion of N2 to NH3, which is comprised of the basic structure of [Fe-S2-Mo]. This material showed high activity of 8.7 mgNH3 mgFe -1 h-1 (24 µgNH3 cm-2 h-1) with an excellent faradaic efficiency of 27% for the conversion of N2 to NH3 in aqueous medium. It was demonstrated that the Fe1 single atom on [Fe-S2-Mo] under the optimal negative potential favors the reduction of N2 to NH3 over the competitive proton reduction to H2. Operando X-ray absorption and simulations combined with theoretical DFT calculations provided the first and important insights on the particular electron-mediating and catalytic roles of the [Fe-S2-Mo] motifs and Fe1, respectively, on this two-dimensional (2D) molecular layer slab.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Chem Sci
Year:
2020
Document type:
Article