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Two Isostructural Titanium Metal-Organic Frameworks for Light Hydrocarbon Separation.
Sun, Yayong; Gao, Mei-Yan; Sun, Yuexin; Lu, Dong-Fei; Wang, Fei; Zhang, Jian.
Affiliation
  • Sun Y; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China.
  • Gao MY; School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, P. R. China.
  • Sun Y; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China.
  • Lu DF; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China.
  • Wang F; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China.
  • Zhang J; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China.
Inorg Chem ; 60(18): 13955-13959, 2021 Sep 20.
Article in En | MEDLINE | ID: mdl-34498867
ABSTRACT
Presented here is the light hydrocarbon separation of titanium metal-organic frameworks (Ti-MOFs). Compared with the cyclic Ti-oxo cluster (Ti8O8(CO2)16, Ti8Ph), porous structures of FIR-125 and FIR-126 (FIR = Fujian Institute Research) can effectively improve the adsorption amounts of light hydrocarbons. The introduction of different functional groups and Ti-oxo clusters with small window sizes enables them to exhibit the highly selective separation of C2 and C3 hydrocarbons versus methane in an ambient atmosphere. The results show that Ti-MOFs are potential porous adsorbents for the separation of light hydrocarbons.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Inorg Chem Year: 2021 Document type: Article
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Inorg Chem Year: 2021 Document type: Article