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SERS-active WO3-x thin films with tunable surface plasmon resonance induced by defects from thermal treatment.
Shi, Yuze; Liu, Qingyou; Hong, Ruijin; Tao, Chunxian; Wang, Qi; Lin, Hui; Han, Zhaoxia; Zhang, Dawei.
Affiliation
  • Shi Y; Engineering Research Center of Optical Instrument and System, Ministry of Education and Shanghai Key Lab of Modern Optical System, University of Shanghai for Science and Technology, No.516 Jungong Road, Shanghai 200093, China.
  • Liu Q; Key Laboratory of High-temperature and High-pressure Study of the Earth's Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China.
  • Hong R; Engineering Research Center of Optical Instrument and System, Ministry of Education and Shanghai Key Lab of Modern Optical System, University of Shanghai for Science and Technology, No.516 Jungong Road, Shanghai 200093, China. Electronic address: rjhong@usst.edu.cn.
  • Tao C; Engineering Research Center of Optical Instrument and System, Ministry of Education and Shanghai Key Lab of Modern Optical System, University of Shanghai for Science and Technology, No.516 Jungong Road, Shanghai 200093, China.
  • Wang Q; Engineering Research Center of Optical Instrument and System, Ministry of Education and Shanghai Key Lab of Modern Optical System, University of Shanghai for Science and Technology, No.516 Jungong Road, Shanghai 200093, China.
  • Lin H; Engineering Research Center of Optical Instrument and System, Ministry of Education and Shanghai Key Lab of Modern Optical System, University of Shanghai for Science and Technology, No.516 Jungong Road, Shanghai 200093, China.
  • Han Z; Engineering Research Center of Optical Instrument and System, Ministry of Education and Shanghai Key Lab of Modern Optical System, University of Shanghai for Science and Technology, No.516 Jungong Road, Shanghai 200093, China.
  • Zhang D; Engineering Research Center of Optical Instrument and System, Ministry of Education and Shanghai Key Lab of Modern Optical System, University of Shanghai for Science and Technology, No.516 Jungong Road, Shanghai 200093, China.
Spectrochim Acta A Mol Biomol Spectrosc ; 268: 120686, 2022 Mar 05.
Article in En | MEDLINE | ID: mdl-34890874
ABSTRACT
A series of WO3-x thin films with defects were obtained by thermal treatments from laser irradiation and annealing, respectively. The corresponding tunability of localized surface plasmon resonance properties and the enhancement of Raman scattering intensity were realized due to the defects in the WO3-x thin films after thermal treatments. With the changes of either laser power or annealing temperature, the crystalline quality of WO3-x thin film was declined with a red shift of the surface plasmon resonance wavelength from 464 nm to 482 nm. The as-treated WO3-x film shows good uniformity and reproducibility in Surface-enhanced Raman spectroscopy measurement, the detection limit for dye methylene blue can reach 10-8 mol/L, and enhancement factor is 1.38 × 106. Furthermore, the simulation result of finite-difference time-domain showed a substantial agreement with experimental results.
Key words

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Spectrochim Acta A Mol Biomol Spectrosc Journal subject: BIOLOGIA MOLECULAR Year: 2022 Document type: Article Affiliation country: China

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Spectrochim Acta A Mol Biomol Spectrosc Journal subject: BIOLOGIA MOLECULAR Year: 2022 Document type: Article Affiliation country: China