Mg/Li@GCN as highly active visible light responding 2D photocatalyst for wastewater remediation application.

ABSTRACT

In this study, a highly visible light responding 2D photocatalytic material has been prepared and analysed for its potential for photodegradation of organic pollutants. The pristine GCN has been co-doped with Mg/Li using the facile synthesis route. The prepared photocatalytic materials were then analysed using characterisation techniques like X-ray diffraction (XRD), Fourier-transform infrared (FTIR) spectroscopy, diffuse reflectance spectra (DRS) and photoluminescence spectroscopy (PL) analysis. The prepared samples were analysed for photocatalytic degradation analysis towards methylene blue dye. The apparent rate constant value increased up to 5.4 times in the case of the GCNML (0.5,2) sample in comparison to GCNP. In addition, the GCNML (0.5,2) sample was also analysed for degradation of crystal violet (CV) (97% in 80 min), rose bengal (RB) (84% in 120 min) and methyl orange (MO) (45% in 120 min) dyes. The result obtained from the study confirmed that GCNML (0.5,2) can act as a potential photocatalyst for wastewater remediation application.