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Formation of a meltable purinate metal-organic framework and its glass analogue.
Bumstead, Alice M; Castillo-Blas, Celia; Pakamore, Ignas; Thorne, Michael F; Sapnik, Adam F; Chester, Ashleigh M; Robertson, Georgina; Irving, Daniel J M; Chater, Philip A; Keen, David A; Forgan, Ross S; Bennett, Thomas D.
Affiliation
  • Bumstead AM; Department of Materials Science and Metallurgy, University of Cambridge, Cambridge, CB3 0FS, UK. tdb35@cam.ac.uk.
  • Castillo-Blas C; Department of Materials Science and Metallurgy, University of Cambridge, Cambridge, CB3 0FS, UK. tdb35@cam.ac.uk.
  • Pakamore I; WestCHEM, School of Chemistry, The University of Glasgow, University Avenue, Glasgow, G12 8QQ, UK.
  • Thorne MF; Department of Materials Science and Metallurgy, University of Cambridge, Cambridge, CB3 0FS, UK. tdb35@cam.ac.uk.
  • Sapnik AF; Department of Materials Science and Metallurgy, University of Cambridge, Cambridge, CB3 0FS, UK. tdb35@cam.ac.uk.
  • Chester AM; Department of Materials Science and Metallurgy, University of Cambridge, Cambridge, CB3 0FS, UK. tdb35@cam.ac.uk.
  • Robertson G; Department of Materials Science and Metallurgy, University of Cambridge, Cambridge, CB3 0FS, UK. tdb35@cam.ac.uk.
  • Irving DJM; Diamond Light Source Ltd, Diamond House, Harwell Campus, Didcot, Oxfordshire, OX11 0DE, UK.
  • Chater PA; Diamond Light Source Ltd, Diamond House, Harwell Campus, Didcot, Oxfordshire, OX11 0DE, UK.
  • Keen DA; ISIS Facility, Rutherford Appleton Laboratory, Harwell Campus, Didcot, Oxfordshire, OX11 0QX, UK.
  • Forgan RS; WestCHEM, School of Chemistry, The University of Glasgow, University Avenue, Glasgow, G12 8QQ, UK.
  • Bennett TD; Department of Materials Science and Metallurgy, University of Cambridge, Cambridge, CB3 0FS, UK. tdb35@cam.ac.uk.
Chem Commun (Camb) ; 59(6): 732-735, 2023 Jan 17.
Article in En | MEDLINE | ID: mdl-36541403
ABSTRACT
The chemistries that can be incorporated within melt-quenched zeolitic imidazolate framework (ZIF) glasses are currently limited. Here we describe the preparation of a previously unknown purine-containing ZIF which we name ZIF-UC-7. We find that it melts and forms a glass at one of the lowest temperatures reported for 3D hybrid frameworks.

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2023 Document type: Article Affiliation country: Reino Unido

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2023 Document type: Article Affiliation country: Reino Unido