Organic-Inorganic Porphyrinoid Frameworks for Biomolecule Sensing.
ACS Sens
; 8(2): 443-464, 2023 02 24.
Article
in En
| MEDLINE
| ID: mdl-36683281
ABSTRACT
Porphyrinoids and their analogous compounds play an important role in biosensing applications on account of their unique and versatile catalytic, coordination, photophysical, and electrochemical properties. Their remarkable arrays of properties can be finely tuned by synthetically modifying the porphyrinoid ring and varying the various structural parameters such as peripheral functionalization, metal coordination, and covalent or physical conjugation with other organic or inorganic scaffolds such as nanoparticles, metal-organic frameworks, and polymers. Porphyrinoids and their organic-inorganic conjugates are not only used as responsive materials but also utilized for the immobilization and embedding of biomolecules for applications in wearable devices, fast sensing devices, and other functional materials. The present review delineates the impact of different porphyrinoid conjugates on their physicochemical properties and their specificity as biosensors in a range of applications. The newest porphyrinoid types and their synthesis, modification, and functionalization are presented along with their advantages and performance improvements.
Key words
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Main subject:
Biosensing Techniques
/
Nanoparticles
/
Metal-Organic Frameworks
/
Wearable Electronic Devices
Language:
En
Journal:
ACS Sens
Year:
2023
Document type:
Article
Affiliation country:
Alemania