Biomass derived reduced-graphene-oxide supported α-Fe2O3/ZnO S-scheme heterostructure: Robust photocatalytic wastewater remediation.

ABSTRACT

The emergence of new diseases and the unplanned industrialization of cities have led to new diseases and the subsequent use of antibiotics. Hence the remediation of wastewater containing antibiotics and their severe pollution has raised serious concerns in recent years. Herein coral-shaped α-Fe2O3/ZnO/reduced graphene oxide (r-GO)-like carbon heterojunction in-situ were prepared from basil seed as a sustainable biomass resource and applied for the photodegradation of the oxytetracycline (OTC) as a typical antibiotic in a helical plug flow photoreactor (HPFPR) via persulfate activation under visible light irradiation. Spectroscopy and electrochemical results confirmed the tunable band structure and quick light absorption, superior charge separation and transfer, satisfactory charge carrier lifetime, and long-term stability for the prepared photocatalyst. The 98% degradation efficiency was achieved for OTC within 90 min fitted by a first-order kinetic model with the rate constant of 0.1248 min-1. The finding proves that HPFPR exhibited a higher degradation rate of OTC by 2.3 times compared to the batch reactor. The 3D computational fluid dynamics (CFD) model confirmed the outstanding performance of the HPFPR. Scavenging experiments integrated with mott Schottky and DRS results revealed that rGO intensifies the S-scheme charge carrier transfer and built-in electric field and reduces the recombination. Finally, this work has substantial potential for the in-situ synthesis of environmental-friendly and large-scale metal oxide heterojunctions in natural carbon supports as well as scale-up and gives novel insights from molecular and engineering points of view into the wastewater remediation processes and clean water production.