A Spiro Phosphamide Catalyzed Enantioselective Proton Transfer of Ylides in a Free Carbene Insertion into N-H Bonds.

Pan, Jia-Bin; Zhang, Xuan-Ge; Shi, Yi-Fan; Han, Ai-Cui; Chen, Yu-Jia; Ouyang, Jing; Li, Mao-Lin; Zhou, Qi-Lin

Pan, Jia-Bin; Zhang, Xuan-Ge; Shi, Yi-Fan; Han, Ai-Cui; Chen, Yu-Jia; Ouyang, Jing; Li, Mao-Lin; Zhou, Qi-Lin.

Affiliation

Pan JB; State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China.
Zhang XG; State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China.
Shi YF; State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China.
Han AC; State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China.
Chen YJ; State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China.
Ouyang J; State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China.
Li ML; State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China.
Zhou QL; State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China.

Angew Chem Int Ed Engl ; 62(15): e202300691, 2023 Apr 03.

Article in En | MEDLINE | ID: mdl-36786065

Key words

Asymmetric Catalysis; Brønsted Acids; Carbenes; N−H Insertion; Phosphamides

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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Angew Chem Int Ed Engl Year: 2023 Document type: Article Affiliation country: China Country of publication: Alemania

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