Abundant nitrogen oxide and weakly acidic environment synergistically promote daytime particulate nitrate pollution.

ABSTRACT

Nitrate is formed through the chemical production of gas-phase nitric acid and subsequent partitioning to the aerosol phase during the daytime. Many studies in the past separated these two aspects, even though they occur simultaneously in the atmosphere. To better understand the nitrate formation mechanism and effectively mitigate its production, it is necessary to consider the synergy between these two mechanisms. For this, we analyze hourly-speciated ambient observations data, with EK&TMA (Empirical Kinetic & Thermodynamic Modeling Approach) map to comprehensively explore the factors controlling nitrate production. Results show that precursor NO2 concentration and aerosol pH, which are related to anthropogenic activities, are the two major factors for chemical kinetics production and gas/particle thermodynamic partitioning processes respectively. Abundant NO2 and weakly acidic environments are favorable conditions for daytime particulate nitrate pollution, thus collaborative control of coal source, vehicle source, and dust source is needed to alleviate nitrate pollution.