Superwettable cellulose acetate-based nanofiber membrane with spider-web structure for highly efficient oily water purification.
Int J Biol Macromol
; 253(Pt 3): 126865, 2023 Dec 31.
Article
in En
| MEDLINE
| ID: mdl-37717870
ABSTRACT
Electrospinning nanofibers membrane has received much attention to remove the insoluble oil from the sewage, while the poor mechanical strength and low oil/water separation efficiency of membranes limit their practical application. Here, we prepared a superwettable deacetylated cellulose acetate (d-CA)-based electrospinning nanofibers membrane simply dipped by bacterial cellulose (BC) and cross-linked with citric acid (CCA) to construct the spider-web structure spontaneously. Compared with the pristine d-CA membrane, the obtained d-CA/BC@CCA membrane exhibits the remarkable oil/water separation performance. The flux and separation efficiency of n-hexane/water emulsion without (SFE) and with (SSE) emulsifier for d-CA/BC@CCA membrane are 9364 L·m-2·h-1·bar-1, 98.34 % and 5479 L·m-2·h-1·bar-1, 99.39 %, respectively, which are mainly attributed to the improved hydrophilicity of its surface and the decreased pore sizes caused by the unique spider-web structure. In addition, d-CA/BC@CCA membrane also possesses the outstanding mechanical properties, the better cycle stability, as well as the excellent durability. This study provides a novel strategy for the construction of the high-performance oil/water separation membrane.
Key words
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Main subject:
Spiders
/
Water Purification
/
Nanofibers
Limits:
Animals
Language:
En
Journal:
Int J Biol Macromol
Year:
2023
Document type:
Article
Publication country:
HOLANDA
/
HOLLAND
/
NETHERLANDS
/
NL
/
PAISES BAJOS
/
THE NETHERLANDS