Unexpected Reduction of a Coordinated Diazapyridinophane Ligand Bound to Chromium(III) Ion Leading to Delocalization of the Unpaired Electron across Two Isolated Pyridine Units.

Krämer, Kristin; Schmitz, Markus; Kelm, Harald; van Wüllen, Christoph; Krüger, Hans-Jörg

Krämer, Kristin; Schmitz, Markus; Kelm, Harald; van Wüllen, Christoph; Krüger, Hans-Jörg.

Affiliation

Krämer K; RPTU Kaiserslautern-Landau, Department of Chemistry, Erwin-Schrödinger Straße 54, 67663, Kaiserslautern, Germany.
Schmitz M; RPTU Kaiserslautern-Landau, Department of Chemistry, Erwin-Schrödinger Straße 54, 67663, Kaiserslautern, Germany.
Kelm H; RPTU Kaiserslautern-Landau, Department of Chemistry, Erwin-Schrödinger Straße 54, 67663, Kaiserslautern, Germany.
van Wüllen C; RPTU Kaiserslautern-Landau, Department of Chemistry and Forschungszentrum OPTIMAS, Erwin-Schrödinger Straße 54, 67663, Kaiserslautern, Germany.
Krüger HJ; RPTU Kaiserslautern-Landau, Department of Chemistry, Erwin-Schrödinger Straße 54, 67663, Kaiserslautern, Germany.

Chemistry ; 30(5): e202301099, 2024 Jan 22.

Article in En | MEDLINE | ID: mdl-37903737

Key words

chromium; electronic structure; pyridine radical anion; tetraazamacrocyclic ligand; π-radical ligand

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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chemistry Journal subject: QUIMICA Year: 2024 Document type: Article Affiliation country: Alemania Country of publication: Alemania

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