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Probing the magnetic and magneto-optical properties of a radical-bridged Tb4 single-molecule magnet.
Mavragani, Niki; Kitos, Alexandros A; Gálico, Diogo A; Mansikkamäki, Akseli; Murugesu, Muralee.
Affiliation
  • Mavragani N; Department of Chemistry and Biomolecular Sciences, University of Ottawa, Ottawa, ON, K1N 6N5, Canada. m.murugesu@uottawa.ca.
  • Kitos AA; Department of Chemistry and Biomolecular Sciences, University of Ottawa, Ottawa, ON, K1N 6N5, Canada. m.murugesu@uottawa.ca.
  • Gálico DA; Department of Chemistry and Biomolecular Sciences, University of Ottawa, Ottawa, ON, K1N 6N5, Canada. m.murugesu@uottawa.ca.
  • Mansikkamäki A; NMR Research Unit, University of Oulu, P.O. Box 8000, FI-90014, Finland.
  • Murugesu M; Department of Chemistry and Biomolecular Sciences, University of Ottawa, Ottawa, ON, K1N 6N5, Canada. m.murugesu@uottawa.ca.
Chem Commun (Camb) ; 59(94): 13970-13973, 2023 Nov 23.
Article in En | MEDLINE | ID: mdl-37937393
ABSTRACT
Reaction of the 1,2,4,5-tetrazine (tz˙-) radical and {Cp*2Tb}+ has yielded a tetranuclear radical-bridged TbIII single-molecule magnet. The strong Ln-radical coupling and the electronic differences of the TbIII ions in [(Cp*2Tb)4(tz˙-)4]·3C6H6 (1) are probed via magnetic, magneto-optical and computational studies.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2023 Document type: Article Affiliation country: Canadá Publication country: ENGLAND / ESCOCIA / GB / GREAT BRITAIN / INGLATERRA / REINO UNIDO / SCOTLAND / UK / UNITED KINGDOM
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2023 Document type: Article Affiliation country: Canadá Publication country: ENGLAND / ESCOCIA / GB / GREAT BRITAIN / INGLATERRA / REINO UNIDO / SCOTLAND / UK / UNITED KINGDOM