Fluorine-free nanoparticle coatings on cotton fabric: comparing the UV-protective and hydrophobic capabilities of silica vs. silica-ZnO nanostructures.
RSC Adv
; 14(7): 4301-4314, 2024 Jan 31.
Article
in En
| MEDLINE
| ID: mdl-38304558
ABSTRACT
Robust, hydrophobic woven cotton fabrics were obtained through the sol-gel dip coating of two different nanoparticle (NP) architectures; silica and silica-ZnO. Water repellency values as high as 148° and relatively low tilt angles for fibrous fabrics (12°) were observed, without the need for fluorinated components. In all cases, this enhanced functionality was achieved with the broad retention of water vapor permeability characteristics, i.e., less than 10% decrease. NP formation routes indicated direct bonding interactions in both the silica and silica-ZnO structures. The physico-chemical effects of NP-compatibilizer (i.e., polydimethoxysilane (PDMS) and n-octyltriethoxysilane (OTES) at different ratios) coatings on cotton fibres indicate that compatibilizer-NP interactions are predominantly physical. Whenever photoactive ZnO-containing additives were used, there was a minor decrease in hydrophobic character, but order of magnitude increases in UV-protective capability (i.e., UPF > 384); properties which were absent in non-ZnO-containing samples. Such water repellency and UPF capabilities were stable to both laundering and UV-exposure, resisting the commonly encountered UV-induced wettability transitions associated with photoactive ZnO. These results suggest that ZnO-containing silica NP coatings on cotton can confer both excellent and persistent surface hydrophobicity as well as UV-protective capability, with potential uses in wearables and functional textiles applications.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
RSC Adv
Year:
2024
Document type:
Article
Country of publication:
Reino Unido