Crystal structure of [1,3-bis-(2,4,6-tri-methyl-phen-yl)imidazolidin-2-yl-idene]di-chlorido-(2-{[(2-methoxyeth-yl)(meth-yl)amino]-meth-yl}benzyl-idene)ruth-en-ium.
Acta Crystallogr E Crystallogr Commun
; 80(Pt 1): 50-53, 2024 Jan 01.
Article
in En
| MEDLINE
| ID: mdl-38312164
ABSTRACT
The title compound, [RuCl2(C33H43N3O)], is an example of a new generation of N,N-dialkyl ruthenium catalysts with an N-Ru coordination bond as part of a six-membered chelate ring. The Ru atom has an Addison τ parameter of 0.244, which indicates a geometry inter-mediate between square-based pyramidal and trigonal-bipyramidal. The complex shows the usual trans arrangement of the two chlorides, with Ru-Cl bond lengths of 2.3515â
(8) and 2.379â
(7)â
Å, and a Cl-Ru-Cl angle of 158.02â
(3)°. One of the chlorine atoms and the atoms of the 2-meth-oxy-N-methyl-N-[(2-methyl-phen-yl)meth-yl]ethane-1-amine group of the title complex display disorder over two positions in a 0.889â
(2) 0.111â
(2) ratio.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Acta Crystallogr E Crystallogr Commun
/
Acta crystallographica. Section E, Crystallographic communications
Year:
2024
Document type:
Article
Affiliation country:
Azerbaiyán
Country of publication:
Reino Unido