Chemodiversity of organic nitrogen emissions from light-duty gasoline vehicles is governed by engine displacements and driving speed.
Sci Total Environ
; 920: 170792, 2024 Apr 10.
Article
in En
| MEDLINE
| ID: mdl-38336060
ABSTRACT
Organic nitrogen emissions from light-duty gasoline vehicles (LDGVs) is believed to play a pivotal role in atmospheric particulate matter (PM) in urban environments. Here, the characterization of organic nitrogen emitted by LDGVs with varying engine displacements at different speed phases was analyzed using a Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) at molecular level. For the LDGV with small engine displacements, the nitrogen-containing organic (CHON) compounds exhibit higher abundance, molecular weight, oxygen content and aromaticity in the extra-high-speed phase. Conversely, for the LDGV with big engine displacements, more CHON compounds with elevated abundance, molecular weight, oxygen content and aromaticity were observed in the low-speed phase. Our study assumed that the formation of CHON compounds emitted from LDGVs is mainly the oxidation reaction during fuel combustion, so the potential precursor-product pairs related to oxidation process were used to study the degree of combustion reaction. The results show that the highest proportion of oxidation occurs during extra-high-speed phase for LDGV with small engine displacements, and during low-speed phase for LDGV with big engine displacements. These results offer a novel perspective for comprehending the mechanism behind vehicle emissions formation and contribute valuable insights for crafting effective air pollution regulations.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Sci Total Environ
Year:
2024
Document type:
Article
Country of publication:
Países Bajos