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Magnetic anisotropy in octahedral Dy(III) and Yb(III) complexes.
Borah, Aditya; Dey, Sourav; Siddiqui, Kehkasha; Gupta, Sandeep K; Rajaraman, Gopalan; Murugavel, Ramaswamy.
Affiliation
  • Borah A; Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, Maharashtra, 400076, India. rmv@chem.iitb.ac.in.
  • Dey S; Department of Chemistry, Jengraimukh College, Majuli, Assam, 785105, India.
  • Siddiqui K; Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, Maharashtra, 400076, India. rmv@chem.iitb.ac.in.
  • Gupta SK; Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, Maharashtra, 400076, India. rmv@chem.iitb.ac.in.
  • Rajaraman G; Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, Delhi, 110016, India.
  • Murugavel R; Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, Maharashtra, 400076, India. rmv@chem.iitb.ac.in.
Dalton Trans ; 53(17): 7263-7267, 2024 Apr 30.
Article in En | MEDLINE | ID: mdl-38618749
ABSTRACT
New organophosphate complexes [Ln(dippH)3(dippH2)3]·(H2O)6, (Ln = Dy, Yb and Y; dippH2 = 2,6-diisopropylphenyl phosphate), displaying octahedral coordination geometry around the metal ion, exhibit unusual slow relaxation of magnetisation, which is investigated through experimental studies and ab initio CASSCF calculations.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Dalton Trans Journal subject: QUIMICA Year: 2024 Document type: Article Affiliation country: India
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Dalton Trans Journal subject: QUIMICA Year: 2024 Document type: Article Affiliation country: India