Carbon-Promoted Pt-Single Atoms Anchored on RuO2 Nanorods to Boost Electrochemical Hydrogen Evolution.
ACS Appl Mater Interfaces
; 16(21): 27504-27510, 2024 May 29.
Article
in En
| MEDLINE
| ID: mdl-38758608
ABSTRACT
While efficient for electrochemical hydrogen evolution reaction (HER), Pt is limited by its cost and rarity. Traditional Pt catalysts and Pt single-atom (aPt) catalysts (Pt-SACs) face challenges in maintaining kinetically favorable HER pathways (Volmer-Tafel) at ultralow Pt loadings. Herein, carbon-promoted aPts were deposited on RuO2 without the addition of reductants. aPts confined on carbon-supported RuO2 nanorods (aPt/RuO2NR/Carbon) promoted "inter-aPts" Tafel. aPt/RuO2NR/Carbon is the Pt-SAC that retained underpotentially deposited H; additionally, its HER onset overpotential was "negative". The aPt/RuO2NR/Carbon exhibited 260-fold higher Pt mass activity (imPt)/turnover frequency (TOF) (522.7 A mg-1/528.4 s-1) than that of commercial Pt/C (1.9 A mg-1/1.9 s-1). In an ultralow Pt loading (0.19 µg cm-2), the HER rate-determining step maintained Volmer-Tafel and the Pt utilization efficiency was 100.3%.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
ACS Appl Mater Interfaces
/
ACS appl. mater. interfaces (Online)
/
ACS applied materials & interfaces (Online)
Journal subject:
BIOTECNOLOGIA
/
ENGENHARIA BIOMEDICA
Year:
2024
Document type:
Article
Country of publication:
Estados Unidos