trans-Di-chlorido-bis-(secnidazole-κN 3)copper(II).
IUCrdata
; 9(Pt 5): x240376, 2024 May.
Article
in En
| MEDLINE
| ID: mdl-38846553
ABSTRACT
The use of acetic acid (HOAc) in a reaction between CuCl2·2H2O and secnid-azole, an active pharmaceutical ingredient useful in the treatment against a variety of anaerobic Gram-positive and Gram-negative bacteria, affords the title complex, [CuCl2(C7H11N3O3)2]. This compound was previously synthesized using ethanol as solvent, although its crystal structure was not reported [Betanzos-Lara et al. (2013 â¸). Inorg. Chim. Acta, 397, 94-100]. In the mol-ecular complex, the Cu2+ cation is situated at an inversion centre and displays a square-planar coordination environment. There is a hydrogen-bonded framework based on inter-molecular O-Hâ¯Cl inter-actions, characterized by Hâ¯Cl separations of 2.28â
(4)â
Å and O-Hâ¯Cl angles of 175â
(3)°. The resulting supra-molecular network is based on R2 2 (18) ring motifs, forming chains in the [010] direction.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
IUCrdata
Year:
2024
Document type:
Article
Affiliation country:
México