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Electrochemical hydrocarboxylation of enol derivatives with CO2: access to ß-acetoxycarboxylic acids.
Ustyuzhanin, Alexander O; Bityukov, Oleg V; Sokolovskiy, Pavel V; Merkulova, Valentina M; Ilovaisky, Alexey I; He, Liang-Nian; Vil', Vera A; Terent'ev, Alexander O.
Affiliation
  • Ustyuzhanin AO; N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospekt, 119991 Moscow, Russian Federation. vil@ioc.ac.ru.
  • Bityukov OV; N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospekt, 119991 Moscow, Russian Federation. vil@ioc.ac.ru.
  • Sokolovskiy PV; N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospekt, 119991 Moscow, Russian Federation. vil@ioc.ac.ru.
  • Merkulova VM; N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospekt, 119991 Moscow, Russian Federation. vil@ioc.ac.ru.
  • Ilovaisky AI; N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospekt, 119991 Moscow, Russian Federation. vil@ioc.ac.ru.
  • He LN; State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China.
  • Vil' VA; N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospekt, 119991 Moscow, Russian Federation. vil@ioc.ac.ru.
  • Terent'ev AO; N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospekt, 119991 Moscow, Russian Federation. vil@ioc.ac.ru.
Chem Commun (Camb) ; 60(62): 8099-8102, 2024 Jul 30.
Article in En | MEDLINE | ID: mdl-38993133
ABSTRACT
Electrochemical hydrocarboxylation of enol acetates with CO2 is developed. The disclosed process provides ß-acetoxycarboxylic acids in 25-66% yields, in contrast to the electrolysis of ketones, silyl enol ethers and vinyl tosylates with CO2, which leads mainly to alcohols.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) / Chem. commun. (Lond., 1996, Online) / Chemical communications (London. 1996. Online) Journal subject: QUIMICA Year: 2024 Document type: Article Country of publication: Reino Unido
Fulltext
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) / Chem. commun. (Lond., 1996, Online) / Chemical communications (London. 1996. Online) Journal subject: QUIMICA Year: 2024 Document type: Article Country of publication: Reino Unido