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A H2@C601H NMR probe for sensitively detecting the supramolecular interactions between a molecular tweezer and C60.
He, Yixing; Yu, Zhi; Jiang, Yanzi; Zhu, Jinjie; Yao, Selina X; Liang, Wenjie; Diederich, François; Saunders, Martin; Xu, Hai.
Affiliation
  • He Y; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China. xhisaac@csu.edu.cn.
  • Yu Z; Institute of Optical Materials and Chemical Biology, Guangxi Key Laboratory of Electrochemical Energy Materials, School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, P. R. China.
  • Jiang Y; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China. xhisaac@csu.edu.cn.
  • Zhu J; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China. xhisaac@csu.edu.cn.
  • Yao SX; Mechanical Engineering Department, University of Vermont, Burlington, Vermont, 05401, USA.
  • Liang W; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China. xhisaac@csu.edu.cn.
  • Diederich F; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China. xhisaac@csu.edu.cn.
  • Saunders M; Department of Chemistry, Yale University, 225 Prospect Street, New Haven CT06511, USA.
  • Xu H; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China. xhisaac@csu.edu.cn.
Chem Commun (Camb) ; 60(66): 8716-8719, 2024 Aug 13.
Article in En | MEDLINE | ID: mdl-39058377
ABSTRACT
Herein, we firstly utilized H2@C60 to monitor the supramolecular interaction between a pH-driven resorcin[4]arene molecular tweezer and C60 with a notable 1H NMR chemical shift change (ca. 0.34 ppm). This work provides a new strategy for detecting weak or complex supramolecular interactions.

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2024 Document type: Article Country of publication: Reino Unido

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2024 Document type: Article Country of publication: Reino Unido