(η6-Benzene)-chlorido-[(S)-2-(4-isopropyl-4,5-di-hydro-oxazol-2-yl)phenolato]ruthenium(II).
IUCrdata
; 9(Pt 7): x240720, 2024 Jul.
Article
in En
| MEDLINE
| ID: mdl-39108939
ABSTRACT
The title compound, [Ru(C12H14NO2)Cl(η6-C6H6)], exhibits a half-sandwich tripod stand structure and crystallizes in the ortho-rhom-bic space group P212121. The arene group is η6 π-coordinated to the Ru atom with a centroid-to-metal distance of 1.6590â
(5)â
Å, with the (S)-2-(4-isopropyl-4,5-di-hydro-oxazol-2-yl)phenolate chelate ligand forming a bite angle of 86.88â
(19)° through its N and phenolate O atoms. The pseudo-octa-hedral geometry assumed by the complex is completed by a chloride ligand. The coordination of the optically pure bidentate ligand induces metal centered chirality onto the complex with a Flack parameter of -0.056.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
IUCrdata
Year:
2024
Document type:
Article
Affiliation country:
Sudáfrica
Country of publication:
Reino Unido