Why is there an "inert" metal center in the active site of nitrile hydratase? Reactivity and ligand dissociation from a five-coordinate Co(III) nitrile hydratase model.

Shearer, J; Kung, I Y; Lovell, S; Kaminsky, W; Kovacs, J A

Shearer, J; Kung, I Y; Lovell, S; Kaminsky, W; Kovacs, J A.

Affiliation

Shearer J; Contribution from the Department of Chemistry, University of Washington, Seattle, Washington 98195, USA.

J Am Chem Soc ; 123(3): 463-8, 2001 Jan 24.

Article in En | MEDLINE | ID: mdl-11456548

Subject(s)

Hydro-Lyases/chemistry; Hydro-Lyases/metabolism; Azides/metabolism; Bacterial Proteins/metabolism; Catalytic Domain; Cobalt/chemistry; Crystallography, X-Ray; Kinetics; Ligands; Models, Molecular; Soil Microbiology; Thermodynamics; Thiocyanates/metabolism

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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Hydro-Lyases Language: En Journal: J Am Chem Soc Year: 2001 Document type: Article Affiliation country: United States Country of publication: United States

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