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A new cationic, chiral catalyst for highly enantioselective Diels-Alder reactions.
Sprott, Kevin T; Corey, E J.
Affiliation
  • Sprott KT; Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA.
Org Lett ; 5(14): 2465-7, 2003 Jul 10.
Article in En | MEDLINE | ID: mdl-12841756
ABSTRACT
[reaction see text] The Diels-Alder reaction of cyclopentadiene and 2-methacrolein is catalyzed by a chiral Lewis acid to form the exo adduct in 96% yield and 96% ee.
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Collection: 01-internacional Database: MEDLINE Main subject: Cations Language: En Journal: Org Lett Journal subject: BIOQUIMICA Year: 2003 Document type: Article Affiliation country: United States
Search on Google
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Collection: 01-internacional Database: MEDLINE Main subject: Cations Language: En Journal: Org Lett Journal subject: BIOQUIMICA Year: 2003 Document type: Article Affiliation country: United States