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A novel methodology for the synthesis of complexes containing long carbon chains linking metal centres: molecular structures of [Ru(dppe)Cp*]2(mu-C14) and [Co3(mu-dppm)(CO)7]2(mu3:mu3-C16).
Antonova, Alla B; Bruce, Michael I; Ellis, Benjamin G; Gaudio, Maryka; Humphrey, Paul A; Jevric, Martyn; Melino, Giovanni; Nicholson, Brian K; Perkins, Gary J; Skelton, Brian W; Stapleton, Bronwin; White, Allan H; Zaitseva, Natasha N.
Affiliation
  • Antonova AB; Department of Chemistry, University of Adelaide, Adelaide, South Australia 5005, Australia.
Chem Commun (Camb) ; (8): 960-1, 2004 Apr 21.
Article in En | MEDLINE | ID: mdl-15069494
ABSTRACT
Elimination of AuX(PR3)(X = halogen, R = Ph, tol) occurs readily in reactions between compounds containing C(sp)- or C(sp2)-X bonds and alkynyl or polyynyl gold(I) complexes; this reaction has been applied to the syntheses of complexes containing a variety of metal centres linked by C(n) chains (n up to 16).
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Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2004 Document type: Article Affiliation country: Australia
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Add to My VHL
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PubMed Links

Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2004 Document type: Article Affiliation country: Australia