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A new route to aristocularine alkaloids: total synthesis of aristoyagonine.
Moreau, Anne; Couture, Axel; Deniau, Eric; Grandclaudon, Pierre.
Affiliation
  • Moreau A; Laboratoire de Chimie Organique Physique, UMR 8009 "Chimie Organique et Macromoléculaire", Université des Sciences et Technologies de Lille, Bâtiment C3(2), F-59655 Villeneuve d'Ascq Cedex, France.
J Org Chem ; 69(13): 4527-30, 2004 Jun 25.
Article in En | MEDLINE | ID: mdl-15202913
ABSTRACT
A short and efficient synthesis of aristocularines, involving the sequential construction of phosphorylated 4-alkoxyisoindolinones, Horner-type reaction, and ultimate cyclization by diaryl ether coupling, is disclosed. The success of this new conceptual approach is demonstrated by the total synthesis of the aristocularine alkaloid aristoyagonine.
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Collection: 01-internacional Database: MEDLINE Main subject: Fumariaceae / Isoquinolines Language: En Journal: J Org Chem Year: 2004 Document type: Article Affiliation country: France
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Collection: 01-internacional Database: MEDLINE Main subject: Fumariaceae / Isoquinolines Language: En Journal: J Org Chem Year: 2004 Document type: Article Affiliation country: France