Vibrational Raman optical activity of carbohydrates.

Barron, L D; Gargaro, A R; Wen, Z Q

Barron, L D; Gargaro, A R; Wen, Z Q.

Affiliation

Barron LD; Chemistry Department, The University, Glasgow, Great Britain.

Carbohydr Res ; 210: 39-49, 1991 Mar 20.

Article in En | MEDLINE | ID: mdl-1878886

ABSTRACT

Vibrational Raman optical activity (R.o.a.) spectra of a range of carbohydrates in aqueous solution, measured in back-scattering between 700 and 1500 cm-1, are presented. Features were revealed that appear to be characteristic of details of the stereochemistry. Effects associated with the glycosidic linkage in di- and oligo-saccharides are prominent.

Subject(s)

Carbohydrates/chemistry; alpha-Cyclodextrins; Arabinose/chemistry; Carbohydrate Conformation; Carbohydrate Sequence; Cellobiose/chemistry; Cyclodextrins/chemistry; Glucose/analogs & derivatives; Glucose/chemistry; Maltose/chemistry; Molecular Sequence Data; Pentoses/chemistry; Spectrum Analysis, Raman; Trisaccharides/chemistry; Vibration; Xylose/chemistry

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Collection: 01-internacional Database: MEDLINE Main subject: Carbohydrates / Alpha-Cyclodextrins Language: En Journal: Carbohydr Res Year: 1991 Document type: Article Affiliation country: United kingdom Country of publication: Netherlands

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