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Synthesis of a new olefin polymerization catalyst supported by an sp3-C donor via insertion of a ligand-appended alkene into the Hf-C bond of a neutral pyridylamidohafnium trimethyl complex.
Domski, Gregory J; Edson, Joseph B; Keresztes, Ivan; Lobkovsky, Emil B; Coates, Geoffrey W.
Affiliation
  • Domski GJ; Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, NY 14853-1301, USA.
Chem Commun (Camb) ; (46): 6137-9, 2008 Dec 14.
Article in En | MEDLINE | ID: mdl-19082098
ABSTRACT
A new living and isoselective propylene polymerization precatalyst was generated via the intramolecular insertion of a ligand-appended vinyl group into the Hf-C bond of a neutral pyridylamidohafnium trimethyl complex.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2008 Document type: Article Affiliation country: United States
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2008 Document type: Article Affiliation country: United States