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Modular syntheses of chiral and achiral C,N-chelated Pd(II)-pyridinylidenes.
Strong, Elizabeth T J; Price, Jacquelyn T; Jones, Nathan D.
Affiliation
  • Strong ET; Department of Chemistry, The University of Western Ontario, London, Ontario, Canada N6A 5B7.
Dalton Trans ; (42): 9123-5, 2009 Nov 14.
Article in En | MEDLINE | ID: mdl-20449186
Modular, high-yielding routes to achiral and chiral, C,N-chelated pyridinylidene complexes of Pd(II) have been developed which rely on oxidative addition of either chloropyridinium imines or aldehydes to Pd(0), respectively, and, in the latter case, subsequent Schiff base formation with chiral primary amines. These protocols succinctly circumvent many of the problems currently associated with the synthesis of chelating pyridinylidenes.

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Dalton Trans Journal subject: QUIMICA Year: 2009 Document type: Article Country of publication: United kingdom

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Dalton Trans Journal subject: QUIMICA Year: 2009 Document type: Article Country of publication: United kingdom