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The first example of metallocene-like coordination mode of THBQ(4-): a mixed-valence heptanucler palladium complex [Pd7(THBQ)2(tben)6](PF6)4.
Asato, Eiji; Kyan, Ayano; Madanbashi, Tomokura; Tamura, Toshihide; Tadokoro, Makoto; Mizuno, Motohiro.
Affiliation
  • Asato E; Department of Chemistry, Biology and Marine Science, Faculty of Science, University of the Ryukyus, Nishihara, Okinawa 903-0213, Japan. asato@sci.u-ryukyu.ac.jp
Chem Commun (Camb) ; 46(8): 1227-8, 2010 Feb 28.
Article in En | MEDLINE | ID: mdl-20449258
The title compound adopts a structure reminiscent of metallocene analogues, in which two disk-like units [Pd(II)(3)(THBQ)(tben)(3)](2+) bind to one naked Pd(0) metal in a sandwich form through each C(6)O(6)(4-) (THBQ(4-)) ring with an eta(6)-binding fashion.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Organometallic Compounds / Palladium / Benzoquinones Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2010 Document type: Article Affiliation country: Japan Country of publication: United kingdom
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Organometallic Compounds / Palladium / Benzoquinones Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2010 Document type: Article Affiliation country: Japan Country of publication: United kingdom