[m × n] metal ion arrays templated by coordination cages.
J Am Chem Soc
; 132(44): 15553-5, 2010 Nov 10.
Article
in En
| MEDLINE
| ID: mdl-20961109
Three-dimensional m × n arrays of metal ion clusters can be assembled as aromatic stacks of planar polynuclear metal complexes within columnar coordination cages. The polynuclear complexes and cage height program the final array structures of the metal ion clusters. Cyclic trinuclear Au(I) complexes (m = 3) assembled into trigonal prismatic arrays (n = 1-3) within the cages and the array structures were clearly shown by X-ray crystallographic analysis. A silver-sandwiched hetero-Au(3)-Ag-Au(3) cluster was also prepared by treating a hexanuclear Au(3)-Au(3) cluster with Ag(I) ion.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
J Am Chem Soc
Year:
2010
Document type:
Article
Affiliation country:
Japan
Country of publication:
United States