Orbital magnetism and spin-orbit effects in the electronic structure of BaIrO3.
Phys Rev Lett
; 105(21): 216407, 2010 Nov 19.
Article
in En
| MEDLINE
| ID: mdl-21231332
ABSTRACT
The electronic structure and magnetism of Ir 5d5 states in nonmetallic, weakly ferromagnetic BaIrO3 are probed with x-ray absorption techniques. Contrary to expectation, the Ir 5d orbital moment is found to be ~1.5 times larger than the spin moment. This unusual, atomiclike nature of the 5d moment is driven by a strong spin-orbit interaction in heavy Ir ions, as confirmed by the nonstatistical large branching ratio at Ir L(2,3) absorption edges. As a consequence, orbital interactions cannot be neglected when addressing the nature of magnetic ordering in BaIrO3. The local moment behavior persists even as the metallic-paramagnetic phase boundary is approached with Sr doping or applied pressure.
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Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Phys Rev Lett
Year:
2010
Document type:
Article
Affiliation country:
United States