Aqua-bis-(4-chloro-2-hy-droxy-benzoato-κO)(1,10-phenanthroline-κN,N')zinc(II).
Acta Crystallogr Sect E Struct Rep Online
; 67(Pt 7): m855-6, 2011 Jul 01.
Article
in En
| MEDLINE
| ID: mdl-21836855
ABSTRACT
In the title compound, [Zn(C(7)H(4)ClO(3))(2)(C(12)H(8)N(2))(H(2)O)], the Zn(II) cation is coordinated by two 4-chloro-2-salicylate anions, one 1,10-phenanthroline ligand and one water mol-ecule in a square-pyramidal coordination geometry; the Zn cation lies 0.4591â
(11)â
Å from the basal plane. The benzene rings of the anions are involved in π-π stacking. The centroid-centroid distance between parallel benzene rings of adjacent mol-ecules is 3.9017â
(17)â
Å, and the centroid-centroid distance between benzene and pyridine rings of adjacent mol-ecules is 3.584â
(2)â
Å. Intra-molecular O-Hâ¯O hydrogen bonding is present.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Acta Crystallogr Sect E Struct Rep Online
Year:
2011
Document type:
Article