Dicyclo-hexyl-ammonium trimethyl-bis-(hydrogen phenyl-phospho-nato)stannate(IV).
Acta Crystallogr Sect E Struct Rep Online
; 67(Pt 12): m1872-3, 2011 Dec 01.
Article
in En
| MEDLINE
| ID: mdl-22199636
ABSTRACT
In the title compound, (C(12)H(24)N)[Sn(CH(3))(3)(C(6)H(6)O(3)P)(2)], the SnMe(3) residues are axially coordinated by two monodentate [PhPO(3)H](-) anions, leading to a trigonal-bipyramidal geometry for the Sn(IV) atom. The two [SnMe(3)(PhPO(3)H)(2)](-) anions in the unit cell are associated into infinite chains along the a axis by O-Hâ¯O hydrogen bonds involving the hy-droxy group of the hydrogen phenyl-phospho-nate ion. The chains inter-act with one another via O-Hâ¯O hydrogen bonds along the c axis. These networks of anions assemble with the dicyclo-hexyl-ammonium ion through N-Hâ¯O hydrogen bonds, forming a three-dimensional network.
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01-internacional
Database:
MEDLINE
Language:
En
Journal:
Acta Crystallogr Sect E Struct Rep Online
Year:
2011
Document type:
Article