Bis[(1,10-phenanthroline-κ(2)N,N')bis-(triphenyl-phosphane-κP)copper(I)] nona-deca-oxidohexa-molybdate(VI).
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 9): m1206-7, 2012 Sep 01.
Article
in En
| MEDLINE
| ID: mdl-22969492
ABSTRACT
The title compound, [Cu(C(12)H(8)N(2))(C(18)H(15)P)(2)](2)[Mo(6)O(19)], was obtained by co-crystallization of the mixed-ligand copper complex cation (1,10-phenanthroline)bis-(triphenyl-phos-phane)copper(I), [Cu(phen)(PPh(3))(2)](+), with the Lindquist polyanion [Mo(6)O(19)](2-). The asymmetric unit consists of half a Lindquist anion and one [Cu(phen)(PPh(3))(2)](+) cationic complex. In the cation, there are intra-molecular π-π inter-actions [centroid-centroid distances = 3.617â
(2) and 3.7272â
(18)â
Å]. This inorganic-organic adduct is connected by C-Hâ¯O hydrogen bonds, forming a two dimensional network lying in the ab plane. These networks are connected by C-Hâ¯π inter-actions into a three-dimensional structure.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Acta Crystallogr Sect E Struct Rep Online
Year:
2012
Document type:
Article
Affiliation country:
Germany