Stereochemistry of intramolecular cyclization of tetra-ß-(1â6)-D-glucosamines and related tetrasaccharides: the role of the conformational stereocontrol and the neighboring group participation.

Titov, Denis V; Gening, Marina L; Gerbst, Alexey G; Chizhov, Alexander O; Tsvetkov, Yury E; Nifantiev, Nikolay E

Stereochemistry of intramolecular cyclization of tetra-ß-(1â6)-D-glucosamines and related tetrasaccharides: the role of the conformational stereocontrol and the neighboring group participation.

Titov, Denis V; Gening, Marina L; Gerbst, Alexey G; Chizhov, Alexander O; Tsvetkov, Yury E; Nifantiev, Nikolay E.

Affiliation

Titov DV; Laboratory of Glycoconjugate Chemistry, N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect 47, 119991 Moscow, Russia.

Carbohydr Res ; 381: 161-78, 2013 Nov 15.

Article in En | MEDLINE | ID: mdl-23312144

Subject(s)

Glucosamine/analogs & derivatives; Oligosaccharides/chemical synthesis; Carbohydrate Conformation; Contraindications; Cyclization; Glucosamine/chemical synthesis; Glucosamine/chemistry; Molecular Sequence Data; Oligosaccharides/chemistry; Quantum Theory; Stereoisomerism

Key words

Anchimeric participation; Conformational stereocontrol; Cyclic oligosaccharides; Intramolecular glycosylation, stereoselectivity; Oligo-ß-(1â6)-d-glucosamines, cyclic

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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Oligosaccharides / Glucosamine Language: En Journal: Carbohydr Res Year: 2013 Document type: Article Affiliation country: RUSSIA Country of publication: Netherlands

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